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International Journal of
Chemistry Studies
ARCHIVES
VOL. 10, ISSUE 2 (2026)
Comparative analysis of metal contents in fresh and used lubricating oils
Authors
Yanda Mohammed Kudu, Ehirim Appolinus I, Ekpewu-Ovie, Raina A, Nwosu, Maduabuchi Joseph, Echenu, Favour A
Abstract
The study compared the analysis of wear metals in fresh and used lubricating oils. Four samples of fresh lubricating oils were categorized as A1, B1, C1 and D1 while their used oil counterparts were designated as A2, B2, C2 and D2 respectively. A dry ash method was adopted for digestion of the samples in a 10:1 (oil: acid) ratio (W/V). The digested sample solutions were subjected to Atomic absorption spectroscopy (AAS) for the detection and quantification of six wear metals. The wear metal concentrations determined for fresh oil were in the range 508-1097.5, 172.1-3557, 574.45-1009.90, 2.5-3.95, 3.15-16.45, 3.05-10.45 ppm for Ca, Mg, Zn, Fe, Cr and Ni respectively, their corresponding oil metal concentrations were in the range of 570.05-934.25, 110.55-400.55, 761.15-1004.39, 2.10-5.50, 2.40-34.55 and 5.40-303.40 ppm respectively for the same metal ions. Among the investigated metal ions of A2, Cr made up 1.54%. The information about these metal concentrations will be helpful in monitoring and maintaining generators and machine engines while also indicating which metals could be quantitatively recovered and thereby being used to solve environmental problems.
Pages:4-8
How to cite this article:
Yanda Mohammed Kudu, Ehirim Appolinus I, Ekpewu-Ovie, Raina A, Nwosu, Maduabuchi Joseph, Echenu, Favour A "Comparative analysis of metal contents in fresh and used lubricating oils". International Journal of Chemistry Studies, Vol 10, Issue 2, 2026, Pages 4-8
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