ARCHIVES
VOL. 7, ISSUE 2 (2023)
Synthesis, crystal-structure refinement characterization and the review of the applications of the transition metal-based supramolecular materials
Authors
Idim V D
Abstract
Transition metal-based supramolecular complex was synthesized via
solution-mediated mechanism under solvothermal conditions by reaction of
alpha-diimine ligand with platinum (II) salt, which led to the formation of a
novel Pt (II) supramolecular complex. The complex was characterized using
mass-spectrophotometer for the determination of the molecular weight of the
complex. The powder x-ray diffraction analysis showed that the complex is pure,
isolable as a bulk phase and stable to the removal of 80% DMF from the ports.
While the spectroscopic characterization revealed that the complex crystalizes
in triclinic space group p(-1) with cell parameters a=4.902Å, b=5.784Å,
c=13.571Å, alpha=87.00Å, beta=88.16Å, gamma=89.55Å. In the zigzag platinum (II)
metal chain, the alternating platinum (II) center is link by two uncoordinated
carboxylic acid spacer. Thus, between the carboxylic acid group, a novel
O-H----O hydrogen bonds and pairs of N-H---Cl hydrogen bonds coordination
entities has been found which function as the connectors to cross-link the
two-dimensional zigzag chains.
Pages:19-22
How to cite this article:
Idim V D "Synthesis, crystal-structure refinement characterization and the review of the applications of the transition metal-based supramolecular materials". International Journal of Chemistry Studies, Vol 7, Issue 2, 2023, Pages 19-22
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