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VOL. 4, ISSUE 1 (2020)
Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography
Authors
Mónica B Reguera, Nadia Galante, Noelia Varela, Mariela I Profeta, María J Jorge, Lilian C Jorge, Jorge M Romero, Nelly L Jorge
Abstract
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied to obtain activation parameters.(DH#=13.07 ± 0.7 Kcal mol-1; DS#=-40,28 ± 0.4calmol-1 K-1; DG#=35.07 ± 0.7 Kcal mol-1) in the 453 – 553 K temperature range.
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Pages:52-55
How to cite this article:
Mónica B Reguera, Nadia Galante, Noelia Varela, Mariela I Profeta, María J Jorge, Lilian C Jorge, Jorge M Romero, Nelly L Jorge "Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography". International Journal of Chemistry Studies, Vol 4, Issue 1, 2020, Pages 52-55
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