International Journal of Chemistry Studies

ISSN: 2581-348X

Vol. 2, Issue 4 (2018)

Oxidative cleavage and rearrangement of olefins using iodosylbenzene or iodine

Author(s): Nizam Havare
The work is about oxidative rearrangement of olefins using a hypervalent λ3-iodine complex. Aryl and alkyl substituted olefins reacts with iodobenzene bortrifluorid diethyl etherate complex, which is subordinated as the hypervalent λ3-iodan complexes, to the corresponding aldehyde and/or ketones up to good yields. A mechanism for the rearrangement reaction was proposed.
Pages: 10-14  |  637 Views  322 Downloads
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